The importance of mold temperature to the development of the desired polymer crystalline structure becomes absolutely crucial in the case of high-performance materials.
Using a mold temperature above a polymer’s Tg ensures a degree of crystallinity high enough to provide for dimensional stability, even if the part must be used at elevated temperatures. But POM is an exception. Why?
Engineering polymers require higher mold temperatures to achieve their ideal structure. The temptation to turn down the mold temperatures can hurt part performance.
Processors are often expected to compensate for ill-advised decisions made earlier in the product-development process. In the case of shrinkage, one of the most common ‘fixes’ is to simply reduce the mold temperature.
Process conditions help determine the difference between the maximum degree of crystallinity that can be achieved in a polymer and the degree that is present in a molded part.
Many processors don’t realize that preserving material characteristics is crucial to product success and failure. The focus here is on molecular weight.
This installment—on elastomers—completes a series, whose theme is to bring more science to the discipline of molding. The overall message: Ask a lot of questions whenever someone posits this or that ‘rule of thumb’ about processing.
While laboratory tests are helpful in determining how polymers behave, you must remember the fundamental differences between laboratory measurements and the real world of plastic processing. Let’s examine semi-crystalline polymers here.